釹鐵硼強力磁鐵燒結物理特性NdFeB Sintered Magnet Feature

NdFeB強力磁鐵燒結磁石其專利權,目前已由日本住友金屬公司轉售給日立金屬公司,屬于異方性磁石,所以較粘結品磁力較強,其磁能積由N-35~N-52(一般80℃) (BH)max在53MGOe,但也因高溫退磁特性而產生各種不同耐溫牌號(M100℃、H120℃、SH150℃----等等)

輻射環

輻射環

磁場配向,放射狀異方性

輻射取向磁環,以其優良的性能,合理的機構在永磁材料中普遍採用,尤其鐵氧體中使用廣泛。但對於國內燒結釹鐵硼行業來說,充磁方向普遍停留在平行取向水平,輻射取向磁環僅在實驗室試製,還未形成批量供貨能力。
我公司在磁鐵成型工藝上取得光輝業績的同時,公司繼續加強對強力磁鐵產品發展的投入,2003年,本公司科技人員在獨立研製的無等靜壓高度一次成型新工藝基礎上,攻克了輻射取向難題,使國內燒結釹鐵硼強力磁鐵生產工藝取得了突破性提高,並於9月28日申請了發明專利(專利號為00125615.7)。目前,此項技術已達到國際先進水準,此項技術的應用在很大程度上推動了釹鐵硼強力磁鐵應用領域的擴展。

牌號 Item/ 性能 Proprtles Residual induction
剩磁感應強度
Br mT (kG)
Coercive Force 矯頑力 bHc KA/m (KOe) Intrinsic Coercive Force 內稟矯頑力 iHc KA/m (KOe) Max Energy Product 最大磁能積 (BH)max KI/m3(MGOe) Max. Appl. Temp.
最高工作溫度 TwC
N35 1170-1220
(11.7-12.2)
≧ 860
( ≧10.8 )
≧ 955
( ≧12 )
263-287
(33-36)
80
N38 1220-1250
(12.2-12.5)
≧ 860
( ≧10.8 )
≧ 955
( ≧12 )
287-310
(36-39)
80
N40 1250-1280
(12.5-12.8)
≧ 860
( ≧10.8 )
≧ 955
( ≧12 )
302-326
(38-41)
80
N42 1280-1320
(12.8-13.2)
≧ 860
( ≧10.8 )
≧ 955
( ≧12 )
318-342
(40-43)
80
N45 1320-1370
(13.2-13.7)
≧ 860
( ≧10.8 )
≧ 955
( ≧12 )
342-366
(43-46)
80
N48 1370-1430
(13.7-14.3)
≧ 836
( ≧10.5 )
≧ 876
( ≧11 )
358-390
(45-49)
80
N50 1390-1440
(13.9-14.4)
≧ 836
( ≧10.5 )
≧ 876
( ≧11 )
374-406
(47-51)
80
N52 1420-1460
(14.2-14.6)
≧ 836
( ≧10.5 )
≧ 876
( ≧11 )
390-422
(49-53)
80
N54 1450-1490
(14.5-14.9)
≧ 836
( ≧10.5 )
≧ 876
( ≧11 )
406-437
(51-55)
80
N55 1460-1520
(14.6-15.2)
≧ 836
( ≧10.5 )
≧ 876
( ≧11 )
414-430
(53-56)
80
N35M 1170-1220
(11.7-12.2)
≧ 868
( ≧10.9 )
≧ 1114
( ≧14 )
263-287
(33-36)
100
N38M 1220-1250
(12.2-12.5)
≧ 899
( ≧11.3 )
≧ 1114
( ≧14 )
287-310
(36-39)
100
N40M 1250-1280
(12.5-12.8)
≧ 923
( ≧11.6 )
≧ 1114
( ≧14 )
302-326
(38-41)
100
N42M 1280-1320
(12.8-13.2)
≧ 955
( ≧12.0 )
≧ 1114
( ≧14 )
318-342
(40-43)
100
N45M 1320-1370
(13.2-13.7)
≧ 995
( ≧12.5 )
≧ 1114
( ≧14 )
342-366
(43-46)
100
N48M 1370-1420
(13.7-14.2)
≧ 995
( ≧12.5 )
≧ 1114
( ≧14 )
358-390
(45-49)
100
N50M 1390-1440
(13.9-14.4)
≧ 995
( ≧12.5 )
≧ 1035
( ≧13 )
374-406
(47-51)
100
N52M 1420-1460
(14.2-14.6)
≧ 995
( ≧12.5 )
≧ 1035
( ≧13 )
382-422
(48-53)
100
N54M 1440-1490
(14.4-14.9)
≧ 995
( ≧12.5 )
≧ 1035
( ≧13 )
398-438
(50-55)
100
N33H 1130-1170
(11.3-11.7)
≧ 836
( ≧10.5 )
≧ 1353
( ≧17 )
247-271
(31-34)
120
N35H 1170-1220
(11.7-12.2)
≧ 868
( ≧10.9 )
≧ 1353
( ≧17 )
263-287
(33-36)
120
N38H 1220-1250
(12.2-12.5)
≧ 899
( ≧11.3 )
≧ 1353
( ≧17 )
287-310
(36-39)
120
N40H 1250-1280
(12.5-12.8)
≧ 923
( ≧11.6 )
≧ 1353
( ≧17 )
302-326
(38-41)
120
N42H 1280-1320
(12.8-13.2)
≧ 955
( ≧12.0 )
≧ 1353
( ≧17 )
318-342
(40-43)
120
N45H 1320-1370
(13.2-13.7)
≧ 995
( ≧12.5 )
≧ 1353
( ≧17 )
342-366
(43-46)
120
N48H 1360-1420
(13.6-14.2)
≧ 1011
( ≧12.7 )
≧ 1273
( ≧16 )
358-390
(45-49)
120
N50H 1390-1440
(13.9-14.4)
≧ 1026
( ≧12.9 )
≧ 1273
( ≧16 )
374-406
(47-51)
120
N52H 1420-1460
(14.2-14.6)
≧ 1035
( ≧13 )
≧ 1273
( ≧16 )
382-422
(48-53)
120
N30SH 1080-1130
(10.8-11.3)
≧ 804
( ≧10.1 )
≧ 1592
( ≧20 )
223-247
(28-31)
150
N33SH 1130-1170
(11.3-11.7)
≧ 844
( ≧10.6 )
≧ 1592
( ≧20 )
247-271
(31-34)
150
N35SH 1170-1220
(11.7-12.2)
≧ 876
( ≧11 )
≧ 1592
( ≧20 )
263-287
(33-36)
150
N38SH 1220-1250
(12.2-12.5)
≧ 907
( ≧11.4 )
≧ 1592
( ≧20 )
287-310
(36-39)
150
N40SH 1250-1280
(12.5-12.8)
≧ 939
( ≧11.8 )
≧ 1592
( ≧20 )
302-326
(38-41)
150
N42SH 1280-1320
(12.8-13.2)
≧ 955
( ≧12 )
≧ 1592
( ≧20 )
318-342
(40-43)
150
N45SH 1320-1370
(13.2-13.7)
≧ 987
( ≧12.4 )
≧ 1512
( ≧19 )
342-366
(43-46)
150
N48SH 1360-1400
(13.6-14.0)
≧ 1011
( ≧12.7 )
≧ 1512
( ≧19 )
358-390
(45-49)
150
N50SH 1390-1420
(13.9-14.2)
≧ 1035
( ≧13)
≧ 1512
( ≧19)
374-406
(47-51)
150
N30UH 1080-1130
(10.8-11.3)
≧ 812
( ≧10.2 )
≧ 1990
( ≧25 )
223-247
(28-31)
180
N33UH 1130-1170
(11.3-11.7)
≧ 852
( ≧10.7 )
≧ 1990
( ≧25 )
247-271
(31-34)
180
N35UH 1170-1220
(11.7-12.2)
≧ 860
( ≧10.8 )
≧ 1990
( ≧25 )
263-287
(33-36)
180
N38UH 1220-1250
(12.2-12.5)
≧ 907
( ≧11.4 )
≧ 1990
( ≧25 )
287-310
(36-39)
180
N40UH 1250-1280
(12.5-12.8)
≧ 923
( ≧11.6 )
≧ 1990
( ≧25 )
326-302
(38-41)
180
N42UH 1280-1320
(12.8-13.2)
≧ 971
( ≧12.2 )
≧ 1990
( ≧25 )
318-342
(40-43)
180
N45UH 1320-1360
(13.2-13.6)
≧ 987
( ≧12.4 )
≧ 1911
( ≧24 )
342-366
(43-46)
180
N48UH 1360-1400
(13.6-14.0)
≧ 1011
( ≧12.7 )
≧ 1911
( ≧24 )
358-390
(45-49)
180
N30EH 1080-1130
(10.8-11.3)
≧ 820
( ≧10.3 )
≧ 2388
( ≧30 )
223-247
(28-31)
200
N33EH 1130-1170
(11.3-11.7)
≧ 860
( ≧10.8 )
≧ 2388
( ≧30 )
247-271
(31-34)
200
N35EH 1170-1220
(11.7-12.2)
≧ 884
( ≧11.1 )
≧ 2388
( ≧30 )
263-287
(33-36)
200
N38EH 1220-1250
(12.2-12.5)
≧ 915
( ≧11.5 )
≧ 2388
( ≧30 )
287-310
(36-39)
200
N40EH 1250-1280
(12.5-12.8)
≧ 947
( ≧11.9 )
≧ 2388
( ≧30 )
302-326
(38-41)
200
N42EH 1280-1320
(12.8-13.2)
≧ 970
( ≧12.2 )
≧ 2388
( ≧30 )
318-342
(40-43)
200
N45EH 1320-1360
(13.2-13.6)
≧ 979
( ≧12.3 )
≧ 2308
( ≧29 )
342-366
(43-46)
200
N28AH 1020-1090
(10.2-10.9)
≧ 772
( ≧9.7 )
≧ 2786
( ≧35 )
199-231
(25-29)
220
N30AH 1070-1130
(10.7-11.3)
≧ 812
( ≧10.2 )
≧ 2786
( ≧35 )
215-247
(27-31)
220
N33AH 1130-1170
(11.2-11.7)
≧ 844
( ≧10.6 )
≧ 2786
( ≧35 )
239-271
(31-34)
220
N35AH 1170-1220
(11.7-12.2)
≧ 883
( ≧11.1 )
≧ 2786
( ≧35 )
263-287
(33-36)
220
N38AH 1220-1250
(12.2-12.5)
≧ 915
( ≧11.5 )
≧ 2786
( ≧35 )
287-310
(36-39)
220
N40AH 1250-1280
(12.5-12.8)
≧ 970
( ≧12.2 )
≧ 2706
( ≧34)
302-326
(38-41)
220

NdFeB燒結性能牌號矩陣表

Hcj/kOe (BH)max/MGOe Temp. max/℃
28 30 33 35 38 40 42 45 48 50 52 54 55
40 (25-29)
N28AH
(10.2-10.9)
(27-31)
N30AH
(10.7-11.3)
(31-34)
N33AH
(11.2-11.7)
(33-36)
N35AH
(11.7-12.2)
(36-39)
N38AH
(12.2-12.5)
(38-41)
N40AH
(12.2-12.8)
220
35 (28-31)
N30EH
(10.8-11.3)
(31-34)
N33EH
(11.3-11.7)
(33-36)
N35EH
(11.7-12.2)
(36-39)
N38EH
(12.2-12.5)
(38-41)
N40EH
(12.2-12.8)
(40-43)
N42EH
(12.8-13.2)
(43-46)
N45EH
(13.2-13.6)
200
30 (28-31)
N30UH
(10.8-11.3)
(31-34)
N33UH
(11.3-11.7)
(33-36)
N35UH
(11.7-12.2)
(36-39)
N38UH
(12.2-12.5)
(38-41)
N40UH
(12.2-12.8)
(40-43)
N42UH
(12.8-13.2)
(43-46)
N45UH
(13.2-13.6)
(45-49)
N48UH
(13.6-14)
180
25 (28-31)
N30SH
(10.8-11.3)
(31-34)
N33SH
(11.3-11.7)
(33-36)
N35SH
(11.7-12.2)
(36-39)
N38SH
(12.2-12.5)
(38-41)
N40SH
(12.5-12.8)
(40-43)
N42SH
(12.8-13.2)
(43-46)
N45SH
(13.2-13.7)
(45-49)
N48SH
(13.6-14)
(47-51)
N50SH
(13.9-14.2)
150
20 (31-34)
N33H
(11.3-11.7)
(33-36)
N35H
(11.7-12.2)
(36-39)
N38H
(12.2-12.5)
(38-41)
N40H
(12.5-12.8)
(40-43)
N42H
(12.8-13.2)
(43-46)
N45H
(13.2-13.7)
(45-49)
N48H
(13.6-14.2)
(47-51)
N50H
(13.9-14.4)
(48-53)
N52H
(14.2-14.6)
120
17 (33-36)
N35M
(11.7-12.2)
(36-39)
N38M
(12.2-12.5)
(38-41)
N40M
(12.5-12.8)
(40-43)
N42M
(12.8-13.2)
(43-46)
N45M
(13.2-13.7)
(45-49)
N48M
(13.6-14.2)
(47-51)
N50M
(13.9-14.4)
(48-53)
N52M
(14.2-14.6)
(50-55)
N54M
(14.4-14.9)
100
14 (33-36)
N35
(11.7-12.2)
(36-39)
N38
(12.2-12.5)
(38-41)
N40
(12.5-12.8)
(40-43)
N42
(12.8-13.2)
(43-46)
N45
(13.2-13.7)
(45-49)
N48
(13.6-14.3)
(47-51)
N50
(13.9-14.4)
(49-53)
N52
(14.2-14.6)
(51-55)
N54
(14.5-14.9)
(53-56)
N55
(14.6-15.2)
80
11 10.5 11 11.5 11.9 12.2 12.5 12.9 13.3 13.6 13.9 14.2 14.5 14.9 15

Br/kGs

晶界擴散(Grain boundary diffusion,“GBD”) 技術是近幾年發展起來的一種可以有效改善燒結釹鐵硼磁體磁性能的技術手段。通過在磁鋼表面形成一層重稀土膜,經真空熱處理使重稀土沿晶界進入磁體內部,同時重稀土原子取代主相晶粒周圍的Nd 原子形成高矯頑力殼層,這種獨特的顯微結構在極低的剩磁下降值基礎上可大幅提升磁體矯頑力。

Grain boundary diffusion(GBD) technology is a technical means developed in recent years that can effectively improve the magnetic properties of sintered NdFeB magnets.By forming a layer of heavy rare earth film on the surface of the magnet, the heavy rare earth enters the interior of the magnet along the grain boundaries through vacuum heat treatment. At the same time, the heavy rare earth atoms replace the Nd atoms around the main phase grains to form a high coercive force shell. This unique The microstructure greatly increases the magnet's coercive force with extremely low Br loss.

擴散前Before diffusion

擴散後After diffusion

晶界擴散原理示意圖Schematic diagram of grain boundary diffusion principle

    與傳統的非擴散磁體NdFeB相比較,晶界擴散工藝的主要優勢體現在:

  1. 相同牌號的磁體,採用晶界擴散方式可大幅降低Dy、Tb使用量,成本更低;
  2. 採用晶界擴散方式可以製備50EH、52UH等傳統工藝無法企及的高綜合磁性能磁體。
  3. *由於濃度梯度的存在,擴散深度受限,故規模量產的擴散磁鋼厚度通常會有一定的限制。

    Compared with the traditional non-diffusion magnet NdFeB, the main advantages of the grain boundary diffusion process are reflected in:

  1. For magnets of the same brand, the use of grain boundary diffusion can greatly reduce the usage of Dy and Tb, and the cost is lower;
  2. The grain boundary diffusion method can be used to prepare magnets with high comprehensive magnetic properties such as 50EH and 52UH that are beyond the reach of traditional processes.
  3. *Due to the existence of concentration gradient, the diffusion depth is limited, so the thickness of diffusion magnet steel for large-scale mass production usually has certain limitations.

牌號 Item/ 性能 Proprtles Residual induction
剩磁感應強度
Br mT (kG)
Coercive Force 矯頑力 bHc KA/m (KOe) Intrinsic Coercive Force 內稟矯頑力 iHc KA/m (KOe) Max Energy Product 最大磁能積 (BH)max KI/m3(MGOe) Max. Appl. Temp.
最高工作溫度 TwC
G55H 1470-1525
(14.7-15.25)
≧ 1106
( ≧13.9 )
≧ 1353
( ≧17 )
414-446
(52-56)
120
G57H 1495-1550
(14.95-15.5)
≧ 1122
( ≧14.1 )
≧ 1353
( ≧17 )
430-462
(54-58)
120
G48SH 1370-1420
(13.7-14.2)
≧ 1011
( ≧13 )
≧ 1592
( ≧20 )
358-390
(45-49)
150
G50SH 1400-1450
(14.0-14.5)
≧1027
(≧13.2)
≧1592
(≧20)
374-406
(47-51)
150
G52SH 1420-1480
(14.2-14.8)
≧1067
(≧13.4)
≧1592
(≧20)
390-422
(49-53)
150
G55SH 1460-1510
(14.6-15.1)
≧1083
(≧13.6)
≧1592
(≧20)
406-438
(51-55)
150
G40UH 1255-1305
(12.55-13.05)
≧939
(≧11.8)
≧1990
(≧25)
302-326
(38-41)
180
G42UH 1285-1335
(12.85-13.35)
≧963
(≧12.1)
≧1990
(≧25)
318-342
(40-43)
180
G45UH 1330-1380
(13.3-13.8)
≧978
(≧12.4)
≧1990
(≧25)
334-366
(42-46)
180
G48UH 1370-1420
(13.7-14.2)
≧1027
(≧12.9)
≧1990
(≧25)
358-390
(45-49)
180
G50UH 1400-1450
(14.0-14.5)
≧1051
(≧13.2)
≧1990
(≧25)
374-406
(47-51)
180
G52UH 1420-1480
(14.2-14.8)
≧1067
(≧13.5)
≧1990
(≧25)
390-422
(49-53)
180
G54UH 1460-1510
(14.6-15.1)
≧1075
(≧13.5)
≧1990
(≧25)
406-438
(51-55)
180
G35EH 1170-1220
(11.7-12.2)
≧883
(≧11.1)
≧2388
(≧30)
263-287
(33-36)
200
G38EH 1220-1270
(12.2-12.7)
≧916
(≧11.5)
≧2388
(≧30)
287-310
(36-39)
200
G40EH 1260-1310
(12.6-13.1)
≧955
(≧12.0)
≧2388
(≧30)
302-334
(38-42)
200
G42EH 1270-1335
(12.7-13.35)
≧955
(≧12.0)
≧2388
(≧30)
310-342
(39-43)
200
G44EH 1290-1350
(12.9-13.5)
≧971
(≧12.2)
≧2388
(≧30)
318-350
(40-44)
200
G45EH 1320-1380
(13.2-13.8)
≧995
(≧12.5)
≧2388
(≧30)
334-366
(42-46)
200
G46EH 1330-1380
(13.3-13.8)
≧1011
(≧12.7)
≧2388
(≧30)
334-366
(42-46)
200
G48EH 1370-1420
(13.7-14.2)
≧1027
(≧12.9)
≧2388
(≧30)
358-390
(45-49)
200
G50EH 1400-1450
(14.0-14.5)
≧1051
(≧13.2)
≧2388
(≧30)
374-406
(47-51)
200
G35AH 1170-1220
(11.7-12.2)
≧891
(≧11.2)
≧2786
(≧35)
263-287
(33-36)
220
G38AH 1220-1270
(12.2-12.7)
≧931
(≧11.7)
≧2786
(≧35)
287-310
(36-39)
220
G40AH 1240-1305
(12.4-13.05)
≧947
(≧11.9)
≧2786
(≧35)
295-326
(37-41)
200
G42AH 1270-1335
(12.7-13.35)
≧963
(≧12.1)
≧2786
(≧35)
310-342
(39-43)
220
G45AH 1320-1380
(13.2-13.8)
≧995
(≧12.5)
≧2786
(≧35)
334-366
(42-46)
220

晶界擴散NdFeB性能牌號矩陣表

Hcj/kOe (BH)max/MGOe Temp. max/℃
35 38 40 42 45(46) 48 50 52 54(55) 57
40 (33-36)
G35AH
(11.7-12.2)
(36-39)
G38AH
(12.2-12.7)
(37-41)
G40AH
(12.4-13.05)
(39-43)
G42AH
(12.7-13.35)
(42-46)
G45AH
(13.2-13.8)
220
35 (33-36)
G35EH
(11.7-12.2)
(36-39)
G38EH
(12.2-12.7)
(38-42)
G40EH
(12.6-13.1)
(39-43)
G42EH
(12.7-13.35)
(42-46)
G46EH
(13.3-13.8)
(45-49)
G48EH
(13.7-14.2)
(47-51)
G50EH
(14.0-14.5)
200
30 (38-41)
G40UH
(12.55-13.05)
(40-43)
G42UH
(12.85-13.35)
(42-46)
G45UH
(13.3-13.8)
(45-49)
G48UH
(13.7-14.2)
(47-51)
G50UH
(14.0-14.5)
(49-53)
G52UH
(14.2-14.8)
(51-55)
G54UH
(14.6-15.1)
180
25 (45-49)
G48SH
(13.7-14.2)
(47-51)
G50SH
(14.0-14.5)
(49-53)
G52SH
(14.2-14.8)
(51-55)
G55SH
(14.6-15.1)
150
20 (45-49)
G48H
(13.6-14.2)
(47-51)
G50H
(13.9-14.4)
(48-53)
G52H
(14.2-14.6)
(52-56)
G55H
(14.7-15.25)
(54-58)
G57H
(14.95-15.5)
120
17 11.7 12.2 12.5 12.9 13.3 13.6 14.0 14.2 14.5 15 15.5 100

Br/kGs